A study on the regeneration of α-tocopherol (vitamin E) by phenolic co-antioxidants in homogeneous hydrocarbon solution is reported. The behavior of some relevant phenols such as BHA, BHT, and trans-resveratrol appears to be nicely predicted by a model based on the knowledge of kinetic and thermochemical data concerning the various reactants. Despite its good reputation as an antioxidant, trans-resveratrol was found only moderately effective (kinh = 2.0 × 105 M-1 s -1 in chlorobenzene at 303 K) and unable to recycle vitamin E.
Amorati R., Ferroni F., Pedulli G.F., Valgimigli L. (2003). Modeling the Co-Antioxidant Behavior of Monofunctional Phenols. Applications to Some Relevant Compounds. JOURNAL OF ORGANIC CHEMISTRY, 68(25), 9654-9658 [10.1021/jo0351825].
Modeling the Co-Antioxidant Behavior of Monofunctional Phenols. Applications to Some Relevant Compounds
Amorati R.;Ferroni F.;Pedulli G. F.
;Valgimigli L.
2003
Abstract
A study on the regeneration of α-tocopherol (vitamin E) by phenolic co-antioxidants in homogeneous hydrocarbon solution is reported. The behavior of some relevant phenols such as BHA, BHT, and trans-resveratrol appears to be nicely predicted by a model based on the knowledge of kinetic and thermochemical data concerning the various reactants. Despite its good reputation as an antioxidant, trans-resveratrol was found only moderately effective (kinh = 2.0 × 105 M-1 s -1 in chlorobenzene at 303 K) and unable to recycle vitamin E.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
