COMMUNICATION: In this communication we report a detailed conformational/tautomeric investigation of 2-mercaptopyridine (2MP), obtained from the combination of two relatively rapid techniques, namely free jet microwave (MW) spectroscopy and core level photoemission spectroscopy. Interestingly, the energies of the corresponding photons lie at opposite extremes: 210-4 for the MW spectroscopy and 5102 eV for the synchrotron radiation, respectively.
S. Melandri, L. Evangelisti, A. Maris, W. Caminati, B. M. Giuliano, V. Feyer, et al. (2010). Rotational and Core Level Spectroscopies As Complementary Techniques in Tautomeric/ Conformational Studies: The Case of 2-Mercaptopyridine. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132, 10269-10271 [10.1021/ja104484b].
Rotational and Core Level Spectroscopies As Complementary Techniques in Tautomeric/ Conformational Studies: The Case of 2-Mercaptopyridine
MELANDRI, SONIA;EVANGELISTI, LUCA;MARIS, ASSIMO;CAMINATI, WALTHER;GIULIANO, BARBARA MICHELA;
2010
Abstract
COMMUNICATION: In this communication we report a detailed conformational/tautomeric investigation of 2-mercaptopyridine (2MP), obtained from the combination of two relatively rapid techniques, namely free jet microwave (MW) spectroscopy and core level photoemission spectroscopy. Interestingly, the energies of the corresponding photons lie at opposite extremes: 210-4 for the MW spectroscopy and 5102 eV for the synchrotron radiation, respectively.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
