New stable [6,6]-methano cycloadducts and fulleropyrazolines containing electron-withdrawing groups have been obtained by the reaction of ethyl diazopiruvate with [60]fullerene. The results obtained by a sistematic study conducted both in thermal and catalytic conditions have provided crucial indications concerning the mechanism of this important cluster opening process in fullerene chemistry.
M. Roberti, B. Natalini, V. Andrisano, R. Seraglia, A. Gioiello, R. Pellicciari (2010). Thermal and catalytic reactions of ethyl diazopiruvate with [60]fullerene. TETRAHEDRON, 66, 7329-7332 [10.1016/j.tet.2010.06.067].
Thermal and catalytic reactions of ethyl diazopiruvate with [60]fullerene
ROBERTI, MARINELLA;ANDRISANO, VINCENZA;
2010
Abstract
New stable [6,6]-methano cycloadducts and fulleropyrazolines containing electron-withdrawing groups have been obtained by the reaction of ethyl diazopiruvate with [60]fullerene. The results obtained by a sistematic study conducted both in thermal and catalytic conditions have provided crucial indications concerning the mechanism of this important cluster opening process in fullerene chemistry.File in questo prodotto:
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