Manganese Hexacyanoferrate (MnHCF) and partially nickel substituted MnHCF were synthesized by simple co-precipitation method. The water content and chemical formula were obtained by TGA and MP-AES measurements, functional groups by FT-IR analysis, the crystal structure by PXRD and a local geometry by XAS-EXAFS spectroscopy. With the addition of nickel, vacancies and water content increased inside the sample. Crystal structure has changed from monoclinic to cubic. Ni disturbed the local structure of Mn, site, however, almost no change was observed in Fe site.
Maisuradze, M., Li, M., Aquilanti, G., Plaisier, J., Giorgetti, M. (2023). Characterization of partially Ni substituted manganese hexacyanoferrate cathode material. MATERIALS LETTERS, 330, 1-3 [10.1016/j.matlet.2022.133259].
Characterization of partially Ni substituted manganese hexacyanoferrate cathode material
Maisuradze M.;Li M.;Giorgetti M.
2023
Abstract
Manganese Hexacyanoferrate (MnHCF) and partially nickel substituted MnHCF were synthesized by simple co-precipitation method. The water content and chemical formula were obtained by TGA and MP-AES measurements, functional groups by FT-IR analysis, the crystal structure by PXRD and a local geometry by XAS-EXAFS spectroscopy. With the addition of nickel, vacancies and water content increased inside the sample. Crystal structure has changed from monoclinic to cubic. Ni disturbed the local structure of Mn, site, however, almost no change was observed in Fe site.File | Dimensione | Formato | |
---|---|---|---|
Giorgetti_Contribution for Special Issue Revision, clean, after revision.pdf
Open Access dal 02/01/2024
Tipo:
Postprint / Author's Accepted Manuscript (AAM) - versione accettata per la pubblicazione dopo la peer-review
Licenza:
Licenza per Accesso Aperto. Creative Commons Attribuzione - Non commerciale - Non opere derivate (CCBYNCND)
Dimensione
509.4 kB
Formato
Adobe PDF
|
509.4 kB | Adobe PDF | Visualizza/Apri |
Giorgetti_SI.docx
Open Access dal 02/01/2024
Tipo:
File Supplementare
Licenza:
Licenza per Accesso Aperto. Creative Commons Attribuzione - Non commerciale - Non opere derivate (CCBYNCND)
Dimensione
1.06 MB
Formato
Microsoft Word XML
|
1.06 MB | Microsoft Word XML | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.