Binary Sequences for Online Electrochemical Impedance Spectroscopy of Battery Cells

Online diagnostic of lithium-ion battery (LIB) cells may have significant impact on chemical energy storage systems. Electrochemical impedance spectroscopy (EIS) is widely used for the characterization of LIBs and could be the most appropriate technique for online diagnostic, but its response time should be shortened. This work investigates the usage of multisine excitation to shorten the measurement time and simplify the hardware implementation for EIS of battery cells. Two types of multisine binary sequences are considered: sigma-delta modulated multisine sequences (SDMSs) and maximum length binary sequences (MLBSs). Their applicability to online and in situ EIS monitoring is evaluated by designing a measurement architecture also suitable to be implemented in a system-on-chip. The calibrated measurement system is compared with a benchtop reference instrument, reporting an RMSE deviation smaller than 5% in the frequency range of interest 1-200 Hz. The realized system is then used for online monitoring of the discharge process of a commercial 18650 LIB cell. The two proposed sequences are compared in terms of accuracy using a digital battery emulator circuit. Both the sequences demonstrated to be suitable for fast measurement and simple hardware integration, enabling online in situ EIS monitoring at cell level.