The reaction of bis(trimethylsilyl)sulphide with bromine at -78°C forms trimethylsilylsulphenyl bromide which reacts with alkenes to give thiiranes. Trimethylsilyl bromide and iodide catalytically desulphurize thiiranes to alkenes. © 1988.
Titolo: | Thiiranes: One-pot synthesis from alkenes, and catalytic desulphurization | |
Autore/i: | Capozzi F.; Capozzi G.; Menichetti S. | |
Autore/i Unibo: | ||
Anno: | 1988 | |
Rivista: | ||
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/S0040-4039(00)80449-9 | |
Abstract: | The reaction of bis(trimethylsilyl)sulphide with bromine at -78°C forms trimethylsilylsulphenyl bromide which reacts with alkenes to give thiiranes. Trimethylsilyl bromide and iodide catalytically desulphurize thiiranes to alkenes. © 1988. | |
Data stato definitivo: | 2022-03-10T14:55:29Z | |
Appare nelle tipologie: | 1.01 Articolo in rivista |
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