The reaction of bis(trimethylsilyl)sulphide with bromine at -78°C forms trimethylsilylsulphenyl bromide which reacts with alkenes to give thiiranes. Trimethylsilyl bromide and iodide catalytically desulphurize thiiranes to alkenes. © 1988.
Capozzi F., Capozzi G., Menichetti S. (1988). Thiiranes: One-pot synthesis from alkenes, and catalytic desulphurization. TETRAHEDRON LETTERS, 29(33), 4177-4180 [10.1016/S0040-4039(00)80449-9].
Thiiranes: One-pot synthesis from alkenes, and catalytic desulphurization
Capozzi F.;
1988
Abstract
The reaction of bis(trimethylsilyl)sulphide with bromine at -78°C forms trimethylsilylsulphenyl bromide which reacts with alkenes to give thiiranes. Trimethylsilyl bromide and iodide catalytically desulphurize thiiranes to alkenes. © 1988.File in questo prodotto:
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