Structural and energetic features of the complex 1,4-difluorobenzene-ammonia have been investigate by rotational spectroscopy. The complex adopts a pi-configuration, with the nitrogen of ammonia in the plane of the aromatic ring. Two weak hydrogen bonds, C-H∙∙∙N and N-H∙∙∙F, represent the linkages between ammonia and 1,4-difluorobenzene.
B. M. Giuliano, L. Evangelisti, A. Maris, W. Caminati (2010). Weak hydrogen bonds in σ-1,4-difluorobenzene-ammonia: a rotational study. CHEMICAL PHYSICS LETTERS, 485, 36-39 [10.1016/j.cplett.2009.12.025].
Weak hydrogen bonds in σ-1,4-difluorobenzene-ammonia: a rotational study
GIULIANO, BARBARA MICHELA;EVANGELISTI, LUCA;MARIS, ASSIMO;CAMINATI, WALTHER
2010
Abstract
Structural and energetic features of the complex 1,4-difluorobenzene-ammonia have been investigate by rotational spectroscopy. The complex adopts a pi-configuration, with the nitrogen of ammonia in the plane of the aromatic ring. Two weak hydrogen bonds, C-H∙∙∙N and N-H∙∙∙F, represent the linkages between ammonia and 1,4-difluorobenzene.File in questo prodotto:
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