The rotational spectra of two isotopologues of the anisole-ammonia molecular complex have been measured with the pulsed jet Fourier transform microwave technique. The obtained rotational and quadrupole coupling constants provide a unequivocal conformational assignment. The NH3 group lies out of the plane of the aromatic ring and it is bonded to anisole via three weak, N-H∙∙∙O, CMe-H∙∙∙N and N-H∙∙∙pi contacts.

Pure Rotational Spectrum and Model Calculations of Anisole−Ammonia

GIULIANO, BARBARA MICHELA;MARIS, ASSIMO;MELANDRI, SONIA;CAMINATI, WALTHER
2009

Abstract

The rotational spectra of two isotopologues of the anisole-ammonia molecular complex have been measured with the pulsed jet Fourier transform microwave technique. The obtained rotational and quadrupole coupling constants provide a unequivocal conformational assignment. The NH3 group lies out of the plane of the aromatic ring and it is bonded to anisole via three weak, N-H∙∙∙O, CMe-H∙∙∙N and N-H∙∙∙pi contacts.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11585/83491
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