Validating far-field deformation styles from the Adjara-Trialeti fold-and-thrust belt to the Greater Caucasus (Georgia) through multi-proxy thermal maturity datasets

Thermal history reconstructions can help to better characterise the geological history of areas that experienced a polyphase tectonic evolution. The integration of published stratigraphic/structural data with new and pre- existing data on thermal maturity (clay mineralogy, Raman spectroscopy, vitrinite reflectance, and pyrolysis) of both surface and subsurface sedimentary successions of a wide region of Georgia including -north to south- the southern Greater Caucasus, the western Kura Basin, and the Adjara-Trialeti fold-and-thrust belt (FTB) provides cogent constraints on its late Mesozoic-Cenozoic tectono-sedimentary evolution. Overall, thermal maturity spans from the low diagenesis (60–80 ◦C) in the Upper Miocene section of the Kura Basin to anchizone-epizone (about 400 ◦C) in the central Greater Caucasus axial zone. In more detail, different maturity trends and thermal histories point to the existence of two domains formed by positive tectonic inver- sion: (i) the Adjara-Trialeti FTB from an Eocene rift basin and (ii) the Greater Caucasus from a Mesozoic rift basin. Multiple thermal indicators, along with stratigraphic/structural evidence, show that the Paleocene section of the Adjara-Trialeti basin fill reached the upper oil window (ca. 115 ◦C) during maximum sedimentary burial and that the whole basin was then exhumed starting from the late Middle Miocene. A positive correlation be- tween thermal maturity and stratigraphic age points to a limited thermal effect of tectonic loading. In the southern Greater Caucasus, thermal maturity increases progressively with stratigraphic age, from ca. 100 ◦C (Upper Eocene) to 400 ◦C (Lower Jurassic), in broad agreement with the reconstructed thickness of the basin-fill succession, thus indicating that most of the thermal maturity was again induced by sedimentary burial. As to the flexural western Kura Basin, its Maikopian (Oligocene-Early Miocene) section reached the oil window (up to ca. 110 ◦C) whereas the Middle-Late Miocene one is immature. The Kakheti ridge -a highly tectonised portion of the Kura Basin- reached immature to early mature conditions.