Symmetrical ditocopheryl disulfides (Toc)2S2 and symmetrical and unsymmetrical ditocopheryl sulfides (Toc)2S were simply prepared under remarkably mild conditions with complete control of the regiochemistry by using δ-, γ-, and β-tocopheryl-N-thiophthalimides (Toc-NSPht) as common starting materials. The roles of sulfur atom(s), H-bond and aryl ring substitution pattern on the antioxidant profile of these new compounds, which were assembled by linking together two tocopheryl units, are also discussed.

Viglianisi C., Vasa K., Tanini D., Capperucci A., Amorati R., Valgimigli L., et al. (2019). Ditocopheryl Sulfides and Disulfides: Synthesis and Antioxidant Profile. CHEMISTRY-A EUROPEAN JOURNAL, 25(38), 9108-9116 [10.1002/chem.201901537].

Ditocopheryl Sulfides and Disulfides: Synthesis and Antioxidant Profile

Amorati R.;Valgimigli L.;Baschieri A.;
2019

Abstract

Symmetrical ditocopheryl disulfides (Toc)2S2 and symmetrical and unsymmetrical ditocopheryl sulfides (Toc)2S were simply prepared under remarkably mild conditions with complete control of the regiochemistry by using δ-, γ-, and β-tocopheryl-N-thiophthalimides (Toc-NSPht) as common starting materials. The roles of sulfur atom(s), H-bond and aryl ring substitution pattern on the antioxidant profile of these new compounds, which were assembled by linking together two tocopheryl units, are also discussed.
2019
Viglianisi C., Vasa K., Tanini D., Capperucci A., Amorati R., Valgimigli L., et al. (2019). Ditocopheryl Sulfides and Disulfides: Synthesis and Antioxidant Profile. CHEMISTRY-A EUROPEAN JOURNAL, 25(38), 9108-9116 [10.1002/chem.201901537].
Viglianisi C.; Vasa K.; Tanini D.; Capperucci A.; Amorati R.; Valgimigli L.; Baschieri A.; Menichetti S.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/694781
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