The rotational spectra of tert-butanol•••14NH3 and tert-butanol•••15NH3 have been investigated and assigned by pulsed jet Fourier transform microwave spectroscopy. According to the values of the 14N quadrupole coupling constants, the complex (where NH3 acts as a proton acceptor) adopts a configuration with an almost linear O-H•••N hydrogen bond. The NH3 moiety undergoes a nearly free rotation.

A rotational study of the molecular complex tert-butanol•••NH3

GIULIANO, BARBARA MICHELA;MARIS, ASSIMO;MELANDRI, SONIA;CAMINATI, WALTHER;
2008

Abstract

The rotational spectra of tert-butanol•••14NH3 and tert-butanol•••15NH3 have been investigated and assigned by pulsed jet Fourier transform microwave spectroscopy. According to the values of the 14N quadrupole coupling constants, the complex (where NH3 acts as a proton acceptor) adopts a configuration with an almost linear O-H•••N hydrogen bond. The NH3 moiety undergoes a nearly free rotation.
B.M.Giuliano; M.C.Castrovilli; A.Maris; S.Melandri; W.Caminati; E.A.Cohen
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11585/68678
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