Different synthetic procedures lead to different coordination polymers (CPs) based either on the trinuclear triangular [Cu3(μ3-OH)(μ-pz)3]2+ or on the mononuclear [Cu(Hpz)3]2+ (Hpz = pyrazole) secondary building units (SBUs), bridged by the flexible glutarate (Glu) dianion. The mononuclear complex [Cu(HGlu)2(Hpz)4] was also obtained as byproduct. One of the CPs based on the trinuclear SBU displays a relevant porosity due to three intersecting channels, accounting for about 40% of the solvent accessible void space.
Forlin, E., Lanza, A., Di Nicola, C., Monari, M., Gazzano, M., Nestola, F., et al. (2018). 1D and 3D coordination polymers based on the Cu3(μ3-OH)(μ-pz)3 and Cu(Hpz)3 SBUs connected by the flexible glutarate dianion. INORGANICA CHIMICA ACTA, 470, 385-392 [10.1016/j.ica.2017.09.004].
1D and 3D coordination polymers based on the Cu3(μ3-OH)(μ-pz)3 and Cu(Hpz)3 SBUs connected by the flexible glutarate dianion
Monari, Magda
;Gazzano, Massimo;
2018
Abstract
Different synthetic procedures lead to different coordination polymers (CPs) based either on the trinuclear triangular [Cu3(μ3-OH)(μ-pz)3]2+ or on the mononuclear [Cu(Hpz)3]2+ (Hpz = pyrazole) secondary building units (SBUs), bridged by the flexible glutarate (Glu) dianion. The mononuclear complex [Cu(HGlu)2(Hpz)4] was also obtained as byproduct. One of the CPs based on the trinuclear SBU displays a relevant porosity due to three intersecting channels, accounting for about 40% of the solvent accessible void space.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
