In this review, the authors describe the role of gold in the chemistry of transition metal carbonyl clusters, a field that has been very active over the past fifty years. Both homo- and heteroleptic Au-containing species of metal carbonyl clusters, fully characterized by X-ray analysis, are discussed across three categories: those which are surface decorated by Au(I) fragments, cluster units connected by naked Au(I) atoms, and Au coreâshell species with metallic gold structures embedded in the cluster frameworks.
Ciabatti, I., Femoni, C., Iapalucci, M.C., Ruggieri, S., Zacchini, S. (2018). The role of gold in transition metal carbonyl clusters. COORDINATION CHEMISTRY REVIEWS, 355, 27-38 [10.1016/j.ccr.2017.07.011].
The role of gold in transition metal carbonyl clusters
Ciabatti, Iacopo
;Femoni, Cristina
;Iapalucci, Maria Carmela;Ruggieri, Silvia;Zacchini, Stefano
2018
Abstract
In this review, the authors describe the role of gold in the chemistry of transition metal carbonyl clusters, a field that has been very active over the past fifty years. Both homo- and heteroleptic Au-containing species of metal carbonyl clusters, fully characterized by X-ray analysis, are discussed across three categories: those which are surface decorated by Au(I) fragments, cluster units connected by naked Au(I) atoms, and Au coreâshell species with metallic gold structures embedded in the cluster frameworks.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.