Peak algebras, paths in the Bruhat graph and Kazhdan–Lusztig polynomials

We give a new characterization of the peak subalgebra of the algebra of quasisymmetric functions and use this to construct a new basis for this subalgebra. As an application of these results we obtain a combinatorial formula for the Kazhdan–Lusztig polynomials which holds in complete generality and is simpler and more explicit than any existing one. We point out that, in a certain sense, this formula cannot be simplified.