The atroposelective desymmetrization of Narylmaleimides was realized by means of a primary amine catalyzed Diels−Alder reaction of enones. The chiral axis as new element of chirality is generated under the remote control of the catalyst that selectively drives the formal Diels−Alder reaction through an exclusive stereochemical outcome.
Florine Eudier, Paolo Righi, Andrea Mazzanti, Alessia Ciogli, Giorgio Bencivenni (2015). Organocatalytic Atroposelective Formal Diels–Alder Desymmetrization ofN-Arylmaleimides. ORGANIC LETTERS, 17, 1728-1731 [10.1021/acs.orglett.5b00509].
Organocatalytic Atroposelective Formal Diels–Alder Desymmetrization ofN-Arylmaleimides
RIGHI, PAOLO;MAZZANTI, ANDREA;BENCIVENNI, GIORGIO
2015
Abstract
The atroposelective desymmetrization of Narylmaleimides was realized by means of a primary amine catalyzed Diels−Alder reaction of enones. The chiral axis as new element of chirality is generated under the remote control of the catalyst that selectively drives the formal Diels−Alder reaction through an exclusive stereochemical outcome.File in questo prodotto:
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