We show here that, in a solvent free environment, a water molecule prefers to form a hydrogen bond with a Cl rather than with a F atom. For this purpose, several isotopologues of chlorofluoromethane-water have been studied by molecular beam Fourier transform rotational spectroscopy
W.Caminati, S.Melandri, A.Maris, P.Ottaviani (2006). Relative Strengths of the O H Cl and O H F Hydrogen Bonds. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 45, 2438-2442 [10.1002/anie.200504486].
Relative Strengths of the O H Cl and O H F Hydrogen Bonds
CAMINATI, WALTHER;MELANDRI, SONIA;MARIS, ASSIMO;OTTAVIANI, PAOLO
2006
Abstract
We show here that, in a solvent free environment, a water molecule prefers to form a hydrogen bond with a Cl rather than with a F atom. For this purpose, several isotopologues of chlorofluoromethane-water have been studied by molecular beam Fourier transform rotational spectroscopyFile in questo prodotto:
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