Aromatic azides are inert toward tributylgermanium hydride under thermal conditions in the absence and in the presence of catalytic amounts of a radical initiator but in the presence of catalytic amounts of benzenethiol undergo fast reaction, yielding reduced anilines and 2-germylated anilines in high overall yields.
L. Benati, G. Bencivenni, R. Leardini, M. Minozzi, D. Nanni, R. Scialpi, et al. (2006). Radical Reduction of Aromatic Azides to Amines with Tributylgermanium Hydride. JOURNAL OF ORGANIC CHEMISTRY, 71, 434-437 [10.1021/jo0521697].
Radical Reduction of Aromatic Azides to Amines with Tributylgermanium Hydride
BENATI, MARIA LUISA;BENCIVENNI, GIORGIO;LEARDINI, RINO;MINOZZI, MATTEO;NANNI, DANIELE;SCIALPI, ROSANNA;SPAGNOLO, PIERO;ZANARDI, GIUSEPPE
2006
Abstract
Aromatic azides are inert toward tributylgermanium hydride under thermal conditions in the absence and in the presence of catalytic amounts of a radical initiator but in the presence of catalytic amounts of benzenethiol undergo fast reaction, yielding reduced anilines and 2-germylated anilines in high overall yields.File in questo prodotto:
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