Aromatic azides are inert toward tributylgermanium hydride under thermal conditions in the absence and in the presence of catalytic amounts of a radical initiator but in the presence of catalytic amounts of benzenethiol undergo fast reaction, yielding reduced anilines and 2-germylated anilines in high overall yields.
Radical Reduction of Aromatic Azides to Amines with Tributylgermanium Hydride / L. Benati; G. Bencivenni; R. Leardini; M. Minozzi; D. Nanni; R. Scialpi; P. Spagnolo; G. Zanardi. - In: JOURNAL OF ORGANIC CHEMISTRY. - ISSN 0022-3263. - STAMPA. - 71:(2006), pp. 434-437. [10.1021/jo0521697]
Radical Reduction of Aromatic Azides to Amines with Tributylgermanium Hydride
BENATI, MARIA LUISA;BENCIVENNI, GIORGIO;LEARDINI, RINO;MINOZZI, MATTEO;NANNI, DANIELE;SCIALPI, ROSANNA;SPAGNOLO, PIERO;ZANARDI, GIUSEPPE
2006
Abstract
Aromatic azides are inert toward tributylgermanium hydride under thermal conditions in the absence and in the presence of catalytic amounts of a radical initiator but in the presence of catalytic amounts of benzenethiol undergo fast reaction, yielding reduced anilines and 2-germylated anilines in high overall yields.File in questo prodotto:
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