The dimer of acrylic acid can exist in two forms, depending on the entgegen or zusammen orientations of the two allyl groups. The latter one (zusammen) has a permanent value of the mub dipole moment component, which allowed measuring its pulsed jet Fourier transform microwave (MW) spectrum. From the tunneling splitting, originating in the concerted proton transfer of the two carboxylic hydrogen atoms and measured for four isotopologues of such a bimolecule, we could determine the barrier and dynamics of the proton transfer.
G. Feng, L. B. Favero, A. Maris, A. Vigorito, W. Caminati, R. Meyer (2012). Proton Transfer in Homodimers of Carboxylic Acids: The Rotational Spectrum of the Dimer of Acrylic Acid. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 134(46), 19281-19286 [10.1021/ja309627m].
Proton Transfer in Homodimers of Carboxylic Acids: The Rotational Spectrum of the Dimer of Acrylic Acid
FENG, GANG;MARIS, ASSIMO;CAMINATI, WALTHER;
2012
Abstract
The dimer of acrylic acid can exist in two forms, depending on the entgegen or zusammen orientations of the two allyl groups. The latter one (zusammen) has a permanent value of the mub dipole moment component, which allowed measuring its pulsed jet Fourier transform microwave (MW) spectrum. From the tunneling splitting, originating in the concerted proton transfer of the two carboxylic hydrogen atoms and measured for four isotopologues of such a bimolecule, we could determine the barrier and dynamics of the proton transfer.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
