Two 1:1 adducts of ammonia with ethanol have been characterized by using pulsed-jet FT microwave spectroscopy. They are formed with two different (trans and gauche), stable conformers of ethanol. Several internal-dynamics effects are reflected in the features of the rotational spectra. The trans complex shows the tunneling effects owing to internal rotation of both ammonia and the methyl group. The rotational transitions of the gauche species exhibit a small splitting that is related to tunneling through the potential-energy barrier between the two equivalent minima.
B.M. Giuliano, L.B. Favero, A. Maris, W. Caminati (2012). Shapes and internal dynamics of the 1:1 adducts of ammonia with trans and gauche ethanol: a rotational study. CHEMISTRY-A EUROPEAN JOURNAL, 18(40), 12759-12763 [10.1002/chem.201201664].
Shapes and internal dynamics of the 1:1 adducts of ammonia with trans and gauche ethanol: a rotational study.
GIULIANO, BARBARA MICHELA;MARIS, ASSIMO;CAMINATI, WALTHER
2012
Abstract
Two 1:1 adducts of ammonia with ethanol have been characterized by using pulsed-jet FT microwave spectroscopy. They are formed with two different (trans and gauche), stable conformers of ethanol. Several internal-dynamics effects are reflected in the features of the rotational spectra. The trans complex shows the tunneling effects owing to internal rotation of both ammonia and the methyl group. The rotational transitions of the gauche species exhibit a small splitting that is related to tunneling through the potential-energy barrier between the two equivalent minima.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
