The rotational spectrum of 2,20-biphenol has been investigated by millimeter wave absorption free jet spectroscopy. The two sides of the phenyl rings with attached the hydroxyl group form a dihedral angle of 112.78. Each hydroxyl group is nearly co-planar to the ring to which it belongs, and points towards the p system of the adjacent ring.
Titolo: | Atropisomerism in bisphenols: free jet absorption millimeter wave study of 2,2’-biphenol |
Autore/i: | OTTAVIANI, PAOLO; MARIS, ASSIMO; CAMINATI, WALTHER |
Autore/i Unibo: | |
Anno: | 2004 |
Rivista: | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1016/j.molstruc.2003.12.048 |
Abstract: | The rotational spectrum of 2,20-biphenol has been investigated by millimeter wave absorption free jet spectroscopy. The two sides of the phenyl rings with attached the hydroxyl group form a dihedral angle of 112.78. Each hydroxyl group is nearly co-planar to the ring to which it belongs, and points towards the p system of the adjacent ring. |
Data prodotto definitivo in UGOV: | 2005-10-10 12:25:45 |
Appare nelle tipologie: | 1.01 Articolo in rivista |
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