The rotational spectrum of 2,20-biphenol has been investigated by millimeter wave absorption free jet spectroscopy. The two sides of the phenyl rings with attached the hydroxyl group form a dihedral angle of 112.78. Each hydroxyl group is nearly co-planar to the ring to which it belongs, and points towards the p system of the adjacent ring.
Atropisomerism in bisphenols: free jet absorption millimeter wave study of 2,2’-biphenol / OTTAVIANI P.; MARIS A.; CAMINATI W.. - In: JOURNAL OF MOLECULAR STRUCTURE. - ISSN 0022-2860. - STAMPA. - 695/696:(2004), pp. 353-356. [10.1016/j.molstruc.2003.12.048]
Atropisomerism in bisphenols: free jet absorption millimeter wave study of 2,2’-biphenol
OTTAVIANI, PAOLO;MARIS, ASSIMO;CAMINATI, WALTHER
2004
Abstract
The rotational spectrum of 2,20-biphenol has been investigated by millimeter wave absorption free jet spectroscopy. The two sides of the phenyl rings with attached the hydroxyl group form a dihedral angle of 112.78. Each hydroxyl group is nearly co-planar to the ring to which it belongs, and points towards the p system of the adjacent ring.File in questo prodotto:
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