NBR-Rich Nanofibrous Membranes for Hindering Composite Delamination: Comparison of the Performance Obtained Using Liquid and Photocrosslinked Rubber

This work compares the delamination behavior of epoxy CFRPs nano-modified with nitrile butadiene rubber/polyethylene oxide (NBR/PEO) blend nanofibrous membranes with a rubber content of 70 wt%. While the electrospun mat is able to retain the nanofibrous structure even without crosslinking, photocrosslinking is also carried to evaluate the potential different efficacy on the delamination hindering. Double cantilever beam (DCB) and end-notched flexure (ENF) tests show significant improvements of the energy release rates (G) both in Mode I (up to ≈4 times) and Mode II (up to ≈1.5 times). In particular, the presence of “liquid” rubber (uncrosslinked mat) leads to the best reinforcing action in Mode I, while the crosslinked membrane gives the highest delamination hindering in Mode II.