Composite anode material based on Fe3O4 and reduced graphene oxide is prepared by base-catalysed co-precipitation and sonochemical dispersion. Structural and morphological characterizations demonstrate an effective and homogeneous embedding of Fe3O4 nanoparticles in the carbonaceous matrix. Electrochemical characterization highlights specific capacities higher than 1000 mAh g−1 at 1C, while a capacity of 980 mAhg−1 is retained at 4C, with outstanding cycling stability. These results demonstrate a synergistic effect by nanosize morphology of Fe3O4 and inter-particle conductivity of graphene nanosheets, which also contribute to enhancing the mechanical and cycling stability of the electrode. The outstanding capacity delivered at high rates suggests a possible application of the anode material for high-power systems.
Staffolani Antunes, Darjazi Hamideh, Carbonari Gilberto, Maroni Fabio, Gabrielli Serena, Nobili Francesco. (2021). Fe3O4/graphene composite anode material for fast-charging li-ion batteries. MOLECULES, 26(14), 1-14 [10.3390/molecules26144316].
Fe3O4/graphene composite anode material for fast-charging li-ion batteries
Staffolani Antunes;
2021
Abstract
Composite anode material based on Fe3O4 and reduced graphene oxide is prepared by base-catalysed co-precipitation and sonochemical dispersion. Structural and morphological characterizations demonstrate an effective and homogeneous embedding of Fe3O4 nanoparticles in the carbonaceous matrix. Electrochemical characterization highlights specific capacities higher than 1000 mAh g−1 at 1C, while a capacity of 980 mAhg−1 is retained at 4C, with outstanding cycling stability. These results demonstrate a synergistic effect by nanosize morphology of Fe3O4 and inter-particle conductivity of graphene nanosheets, which also contribute to enhancing the mechanical and cycling stability of the electrode. The outstanding capacity delivered at high rates suggests a possible application of the anode material for high-power systems.File | Dimensione | Formato | |
---|---|---|---|
Fe3o4graphene composite anode material for fast-charging li-ion batteries.pdf
accesso aperto
Tipo:
Versione (PDF) editoriale
Licenza:
Licenza per Accesso Aperto. Creative Commons Attribuzione (CCBY)
Dimensione
2.51 MB
Formato
Adobe PDF
|
2.51 MB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.