Composite anode material based on Fe3O4 and reduced graphene oxide is prepared by base-catalysed co-precipitation and sonochemical dispersion. Structural and morphological characterizations demonstrate an effective and homogeneous embedding of Fe3O4 nanoparticles in the carbonaceous matrix. Electrochemical characterization highlights specific capacities higher than 1000 mAh g−1 at 1C, while a capacity of 980 mAhg−1 is retained at 4C, with outstanding cycling stability. These results demonstrate a synergistic effect by nanosize morphology of Fe3O4 and inter-particle conductivity of graphene nanosheets, which also contribute to enhancing the mechanical and cycling stability of the electrode. The outstanding capacity delivered at high rates suggests a possible application of the anode material for high-power systems.

Staffolani, A., Darjazi, H., Carbonari, G., Maroni, F., Gabrielli, S., Nobili, Francesco. (2021). Fe3O4/graphene composite anode material for fast-charging li-ion batteries. MOLECULES, 26(14), 1-14 [10.3390/molecules26144316].

Fe3O4/graphene composite anode material for fast-charging li-ion batteries

Staffolani Antunes;
2021

Abstract

Composite anode material based on Fe3O4 and reduced graphene oxide is prepared by base-catalysed co-precipitation and sonochemical dispersion. Structural and morphological characterizations demonstrate an effective and homogeneous embedding of Fe3O4 nanoparticles in the carbonaceous matrix. Electrochemical characterization highlights specific capacities higher than 1000 mAh g−1 at 1C, while a capacity of 980 mAhg−1 is retained at 4C, with outstanding cycling stability. These results demonstrate a synergistic effect by nanosize morphology of Fe3O4 and inter-particle conductivity of graphene nanosheets, which also contribute to enhancing the mechanical and cycling stability of the electrode. The outstanding capacity delivered at high rates suggests a possible application of the anode material for high-power systems.
2021
Staffolani, A., Darjazi, H., Carbonari, G., Maroni, F., Gabrielli, S., Nobili, Francesco. (2021). Fe3O4/graphene composite anode material for fast-charging li-ion batteries. MOLECULES, 26(14), 1-14 [10.3390/molecules26144316].
Staffolani, Antunes; Darjazi, Hamideh; Carbonari, Gilberto; Maroni, Fabio; Gabrielli, Serena; Nobili, Francesco.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/969077
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