Catalytic asymmetric allylic alkylation (AAA) is a wellestablished synthetic protocol to realize complex molecular architectures in a stereochemically defined manner.[1] This method routinely requires preinstalled or in situ formed allylic leaving groups (i.e. acetates, carbonates, phosphates) to generate h3-metal allyl complexes amenable to nucleophilic attack at the allylic termini
Titolo: | Allylic Alcohols: new sustainable sources for catalytic enantioselective alkylation reactions |
Autore/i: | BANDINI, MARCO |
Autore/i Unibo: | |
Anno: | 2011 |
Rivista: | |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1002/anie.201006522 |
Abstract: | Catalytic asymmetric allylic alkylation (AAA) is a wellestablished synthetic protocol to realize complex molecular architectures in a stereochemically defined manner.[1] This method routinely requires preinstalled or in situ formed allylic leaving groups (i.e. acetates, carbonates, phosphates) to generate h3-metal allyl complexes amenable to nucleophilic attack at the allylic termini |
Data prodotto definitivo in UGOV: | 2013-06-13 17:56:34 |
Appare nelle tipologie: | 1.01 Articolo in rivista |
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