Catalytic asymmetric allylic alkylation (AAA) is a wellestablished synthetic protocol to realize complex molecular architectures in a stereochemically defined manner.[1] This method routinely requires preinstalled or in situ formed allylic leaving groups (i.e. acetates, carbonates, phosphates) to generate h3-metal allyl complexes amenable to nucleophilic attack at the allylic termini
Allylic Alcohols: new sustainable sources for catalytic enantioselective alkylation reactions
BANDINI, MARCO
2011
Abstract
Catalytic asymmetric allylic alkylation (AAA) is a wellestablished synthetic protocol to realize complex molecular architectures in a stereochemically defined manner.[1] This method routinely requires preinstalled or in situ formed allylic leaving groups (i.e. acetates, carbonates, phosphates) to generate h3-metal allyl complexes amenable to nucleophilic attack at the allylic terminiFile in questo prodotto:
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