Some 3-trimethylsilyl-2-thiabicyclo[2.2.1]heptenes and heptanes of known configuration were protiodesilylated and the stereochemistry of the reaction was studied. Evidences for a carbanionic intermediate as well as the pivotal role played by the metal counter-ion are described. © 1994, Taylor & Francis Group, LLC. All rights reserved.
Bonini B.F., Masi E., Masiero S. (1994). Stereochemistry of protiodesilylation of 3-trimethylsilyl-2-thiabicyclo[2.2.1]heptenes, heptanes and derivatives. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 95(1-4), 379-380 [10.1080/10426509408034242].
Stereochemistry of protiodesilylation of 3-trimethylsilyl-2-thiabicyclo[2.2.1]heptenes, heptanes and derivatives
Bonini B. F.;Masiero S.
1994
Abstract
Some 3-trimethylsilyl-2-thiabicyclo[2.2.1]heptenes and heptanes of known configuration were protiodesilylated and the stereochemistry of the reaction was studied. Evidences for a carbanionic intermediate as well as the pivotal role played by the metal counter-ion are described. © 1994, Taylor & Francis Group, LLC. All rights reserved.File in questo prodotto:
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