When a chiral dopant is dissolved in an achiral liquid crystal medium, the whole sample organizes into a helical structure with a characteristic length-scale of the order of microns. The relation between chirality at these quite different length-scales can be rationalized by a relatively simple model, which retains the relevant factors coming into play: the molecular shape of the chiral dopant, which controls the chirality of short range intermolecular interactions, and the elastic properties of the nematic environment, which control the restoring torques opposing distortion of the director. In this tutorial review the relation between molecular and phase chirality will be reviewed and several applications of the chiral doping of nematic LCs will be discussed. These range from the exploitation of the amplified molecular chirality for stereochemical purposes (e.g., the determination of the absolute configuration or the enantiomeric excess), to newer applications in physico–chemical fields. The latter take advantage of the periodicity of the chiral field, with length-scales ranging from hundreds to thousands of nanometres, which characterise the cholesteric phase.

S. Pieraccini, S. Masiero, A. Ferrarini, G. P. Spada (2011). CHIRALITY TRANSFER ACROSS LENGTH-SCALES IN NEMATIC LIQUID CRYSTALS: FUNDAMENTALS AND APPLICATIONS. CHEMICAL SOCIETY REVIEWS, 40, 258-271 [10.1039/b924962c].

CHIRALITY TRANSFER ACROSS LENGTH-SCALES IN NEMATIC LIQUID CRYSTALS: FUNDAMENTALS AND APPLICATIONS

PIERACCINI, SILVIA;MASIERO, STEFANO;SPADA, GIAN PIERO
2011

Abstract

When a chiral dopant is dissolved in an achiral liquid crystal medium, the whole sample organizes into a helical structure with a characteristic length-scale of the order of microns. The relation between chirality at these quite different length-scales can be rationalized by a relatively simple model, which retains the relevant factors coming into play: the molecular shape of the chiral dopant, which controls the chirality of short range intermolecular interactions, and the elastic properties of the nematic environment, which control the restoring torques opposing distortion of the director. In this tutorial review the relation between molecular and phase chirality will be reviewed and several applications of the chiral doping of nematic LCs will be discussed. These range from the exploitation of the amplified molecular chirality for stereochemical purposes (e.g., the determination of the absolute configuration or the enantiomeric excess), to newer applications in physico–chemical fields. The latter take advantage of the periodicity of the chiral field, with length-scales ranging from hundreds to thousands of nanometres, which characterise the cholesteric phase.
2011
S. Pieraccini, S. Masiero, A. Ferrarini, G. P. Spada (2011). CHIRALITY TRANSFER ACROSS LENGTH-SCALES IN NEMATIC LIQUID CRYSTALS: FUNDAMENTALS AND APPLICATIONS. CHEMICAL SOCIETY REVIEWS, 40, 258-271 [10.1039/b924962c].
S. Pieraccini; S. Masiero; A. Ferrarini; G. P. Spada
File in questo prodotto:
Eventuali allegati, non sono esposti

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/95775
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 176
  • ???jsp.display-item.citation.isi??? 168
social impact