The pathway of the palladium catalysed methoxycarbonylation of ethene to methyl propanoate has been shown to occur via a hydride rather than a methoxycarbonyl cycle and all the intermediates in this cycle have been unambiguously identified by multinuclear NMR spectroscopy and 13C- labelling.
Synthesis and spectroscopic characterisation of all the intermediates in the Pd-catalysed methoxycarbonylation of ethene / Eastham G.R.; Heaton B.T.; Iggo J.A.; Tooze R.P.; Whyman R.; Zacchini S.. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - STAMPA. - 2000:7(2000), pp. 609-610. [10.1039/b001110j]
Synthesis and spectroscopic characterisation of all the intermediates in the Pd-catalysed methoxycarbonylation of ethene
Zacchini S.
2000
Abstract
The pathway of the palladium catalysed methoxycarbonylation of ethene to methyl propanoate has been shown to occur via a hydride rather than a methoxycarbonyl cycle and all the intermediates in this cycle have been unambiguously identified by multinuclear NMR spectroscopy and 13C- labelling.File in questo prodotto:
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