The pathway of the palladium catalysed methoxycarbonylation of ethene to methyl propanoate has been shown to occur via a hydride rather than a methoxycarbonyl cycle and all the intermediates in this cycle have been unambiguously identified by multinuclear NMR spectroscopy and 13C- labelling.
Eastham G.R., Heaton B.T., Iggo J.A., Tooze R.P., Whyman R., Zacchini S. (2000). Synthesis and spectroscopic characterisation of all the intermediates in the Pd-catalysed methoxycarbonylation of ethene. CHEMICAL COMMUNICATIONS, 2000(7), 609-610 [10.1039/b001110j].
Synthesis and spectroscopic characterisation of all the intermediates in the Pd-catalysed methoxycarbonylation of ethene
Zacchini S.
2000
Abstract
The pathway of the palladium catalysed methoxycarbonylation of ethene to methyl propanoate has been shown to occur via a hydride rather than a methoxycarbonyl cycle and all the intermediates in this cycle have been unambiguously identified by multinuclear NMR spectroscopy and 13C- labelling.File in questo prodotto:
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