The rotational transition measurements of DCO+ in bending-excited states were extended to satellites with higher values of the vibrational angular momentum quantum number, ℓ. A detailed scheme of the energy levels within the ℓ manifolds was derived. The equilibrium rotational constants for all the isotopomers of the formyl ion were derived by means of a proper combination of the perturbed effective rotational constants to compensate for the Coriolis contributions. In this way, an accurate equilibrium structure was obtained.
Dore L., Beninati S., Puzzarini C., Cazzoli G. (2003). Study of vibrational interactions in DCO+ by millimeter-wave spectroscopy and determination of the equilibrium structure of the formyl ion. THE JOURNAL OF CHEMICAL PHYSICS, 118(17), 7857-7862 [10.1063/1.1564042].
Study of vibrational interactions in DCO+ by millimeter-wave spectroscopy and determination of the equilibrium structure of the formyl ion
Dore L.;Beninati S.;Puzzarini C.;Cazzoli G.
2003
Abstract
The rotational transition measurements of DCO+ in bending-excited states were extended to satellites with higher values of the vibrational angular momentum quantum number, ℓ. A detailed scheme of the energy levels within the ℓ manifolds was derived. The equilibrium rotational constants for all the isotopomers of the formyl ion were derived by means of a proper combination of the perturbed effective rotational constants to compensate for the Coriolis contributions. In this way, an accurate equilibrium structure was obtained.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
