Two classes of hydrophilic Pd0 complexes containing P,N and N,N sugar-based ligands were prepared and tested in the Suzuki–Miyaura cross-coupling reaction under environmentally friendly aqueous conditions. The best catalyst was tolerant towards different substrates, and its activity is comparable with the highest values reported so far for reactions in aqueous media [loading 0.0010%, turnover frequency (TOF) 3.5 104 h–1]
Giulia Tarantino, Massimiliano Curcio, Andrea Pica, Andrea Carpentieri, Maria E. Cucciolito, Francesco Ruffo, et al. (2014). Hydrophilic Pd Complexes Based on Sugars for Efficient Suzuki-Miyaura Coupling in Aqueous Systems. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014(25), 4199-4208 [10.1002/ejic.201402456].
Hydrophilic Pd Complexes Based on Sugars for Efficient Suzuki-Miyaura Coupling in Aqueous Systems
Giulia Tarantino;Massimiliano Curcio;Andrea Pica;
2014
Abstract
Two classes of hydrophilic Pd0 complexes containing P,N and N,N sugar-based ligands were prepared and tested in the Suzuki–Miyaura cross-coupling reaction under environmentally friendly aqueous conditions. The best catalyst was tolerant towards different substrates, and its activity is comparable with the highest values reported so far for reactions in aqueous media [loading 0.0010%, turnover frequency (TOF) 3.5 104 h–1]I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
