The progressive replacement of Rh with Ni modulates the electronic as well as chemical properties of body-centered [Rh14_xNi(CO)9-(μ-CO)16]n- clusters (x=0, n=4; x=1, n=5 (shown here); x=2, n=4; x=5, n=2, 3) and prompts multivalence. The complexes obtained are isostructural, but not isoelectronic.

Collini, D., Femoni, C., Iapalucci, M.C., Longoni, G., Svensson, P.H., Zanello, P. (2002). Tuning electronic behavior of carbonyl metal clusters by substitution of interstitial and capping atoms. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 41(19), 3685-3688 [10.1002/1521-3773(20021004)41:19<3685::AID-ANIE3685>3.0.CO;2-7].

Tuning electronic behavior of carbonyl metal clusters by substitution of interstitial and capping atoms

Collini, D;Femoni, C;Iapalucci, MC;Longoni, G;
2002

Abstract

The progressive replacement of Rh with Ni modulates the electronic as well as chemical properties of body-centered [Rh14_xNi(CO)9-(μ-CO)16]n- clusters (x=0, n=4; x=1, n=5 (shown here); x=2, n=4; x=5, n=2, 3) and prompts multivalence. The complexes obtained are isostructural, but not isoelectronic.
2002
Collini, D., Femoni, C., Iapalucci, M.C., Longoni, G., Svensson, P.H., Zanello, P. (2002). Tuning electronic behavior of carbonyl metal clusters by substitution of interstitial and capping atoms. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 41(19), 3685-3688 [10.1002/1521-3773(20021004)41:19<3685::AID-ANIE3685>3.0.CO;2-7].
Collini, D; Femoni, C; Iapalucci, MC; Longoni, G; Svensson, PH; Zanello, P
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/917308
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