Ni-decorated Pd frameworks are displayed by the anionic clusters [Ni16Pd16(CO)40]4- (1) and [Ni26Pd20(CO)54]6- (2) (left and right in the picture, respectively), which are stabilized by a shell of carbonyl ligands. The cluster anions were obtained by reaction of [Ni6(CO)12]2- with [Pd(SEt2)2Cl2] in THF.
Femoni C., Iapalucci M.C., Longoni G., Svensson P.H., Wolowska J. (2000). Homoleptic Carbonyl Ni-Pd Clusters: Synthesis of [Ni16Pd16(CO)40]4- and [Ni26Pd20(CO)54]6- and Structural Characterization of [Nn Bu4]4[Ni16Pd16(CO)40]. ANGEWANDTE CHEMIE. INTERNATIONAL EDITION, 39(9), 1635-1637 [10.1002/(SICI)1521-3773(20000502)39:9<1635::AID-ANIE1635>3.0.CO;2-#].
Homoleptic Carbonyl Ni-Pd Clusters: Synthesis of [Ni16Pd16(CO)40]4- and [Ni26Pd20(CO)54]6- and Structural Characterization of [Nn Bu4]4[Ni16Pd16(CO)40]
Femoni C.;Iapalucci M. C.;Longoni G.;
2000
Abstract
Ni-decorated Pd frameworks are displayed by the anionic clusters [Ni16Pd16(CO)40]4- (1) and [Ni26Pd20(CO)54]6- (2) (left and right in the picture, respectively), which are stabilized by a shell of carbonyl ligands. The cluster anions were obtained by reaction of [Ni6(CO)12]2- with [Pd(SEt2)2Cl2] in THF.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
