Thermolysis of [ Ru,(CO),,] 1 in octane with guaiazulene (7-isopropyl-1.4-dimethylazulene) gave [Ru~(CO),(~,-~~:~~:~~-C,~H,,)] 2 and [Ru,(CO),(p3-q5:q3:q3-Cl5H1,)] 3. The products 2 and 3 have been characterised by spectroscopic techniques and by single-crystal X-ray diffraction. Comparison is made between the two structures of the cluster compounds. Proton NMR and crystal structural data indicate an increased degree of metal-hydrocarbon interaction in 3.

Synthesis and characterisation of guaiazulene derivatives of two ruthenium carbonyl clusters / Johnson, Brian F. G.; Shephard, Douglas S.; Edwards, Andrew J.; Braga, Dario; Parisini, Emilio; Raithby, Paul R.. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - ELETTRONICO. - 20:(1995), pp. 3307-3312. [10.1039/dt9950003307]

Synthesis and characterisation of guaiazulene derivatives of two ruthenium carbonyl clusters

Braga, Dario;Parisini, Emilio;
1995

Abstract

Thermolysis of [ Ru,(CO),,] 1 in octane with guaiazulene (7-isopropyl-1.4-dimethylazulene) gave [Ru~(CO),(~,-~~:~~:~~-C,~H,,)] 2 and [Ru,(CO),(p3-q5:q3:q3-Cl5H1,)] 3. The products 2 and 3 have been characterised by spectroscopic techniques and by single-crystal X-ray diffraction. Comparison is made between the two structures of the cluster compounds. Proton NMR and crystal structural data indicate an increased degree of metal-hydrocarbon interaction in 3.
1995
Synthesis and characterisation of guaiazulene derivatives of two ruthenium carbonyl clusters / Johnson, Brian F. G.; Shephard, Douglas S.; Edwards, Andrew J.; Braga, Dario; Parisini, Emilio; Raithby, Paul R.. - In: JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS. - ISSN 0300-9246. - ELETTRONICO. - 20:(1995), pp. 3307-3312. [10.1039/dt9950003307]
Johnson, Brian F. G.; Shephard, Douglas S.; Edwards, Andrew J.; Braga, Dario; Parisini, Emilio; Raithby, Paul R.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/916060
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