Thermolysis of [ Ru,(CO),,] 1 in octane with guaiazulene (7-isopropyl-1.4-dimethylazulene) gave [Ru~(CO),(~,-~~:~~:~~-C,~H,,)] 2 and [Ru,(CO),(p3-q5:q3:q3-Cl5H1,)] 3. The products 2 and 3 have been characterised by spectroscopic techniques and by single-crystal X-ray diffraction. Comparison is made between the two structures of the cluster compounds. Proton NMR and crystal structural data indicate an increased degree of metal-hydrocarbon interaction in 3.

Johnson, B.F.G., Shephard, D.S., Edwards, A.J., Braga, D., Parisini, E., Raithby, P.R. (1995). Synthesis and characterisation of guaiazulene derivatives of two ruthenium carbonyl clusters. JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS, 20, 3307-3312 [10.1039/dt9950003307].

Synthesis and characterisation of guaiazulene derivatives of two ruthenium carbonyl clusters

Braga, Dario;Parisini, Emilio;
1995

Abstract

Thermolysis of [ Ru,(CO),,] 1 in octane with guaiazulene (7-isopropyl-1.4-dimethylazulene) gave [Ru~(CO),(~,-~~:~~:~~-C,~H,,)] 2 and [Ru,(CO),(p3-q5:q3:q3-Cl5H1,)] 3. The products 2 and 3 have been characterised by spectroscopic techniques and by single-crystal X-ray diffraction. Comparison is made between the two structures of the cluster compounds. Proton NMR and crystal structural data indicate an increased degree of metal-hydrocarbon interaction in 3.
1995
Johnson, B.F.G., Shephard, D.S., Edwards, A.J., Braga, D., Parisini, E., Raithby, P.R. (1995). Synthesis and characterisation of guaiazulene derivatives of two ruthenium carbonyl clusters. JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS, 20, 3307-3312 [10.1039/dt9950003307].
Johnson, Brian F. G.; Shephard, Douglas S.; Edwards, Andrew J.; Braga, Dario; Parisini, Emilio; Raithby, Paul R.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/916060
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