The four clusters Ru~(C~)~~~-~~:~~:~~-C~H~-{~~-CCH~CH~)Z-~,~~, 1, RU~(CO)~~~-~~:~~:~~- CsH4-{7;12-CCH3CHz}~-1,3), 2, Ru~(CO)~~~-~~:~~:~~-~~H~-{~~-~~H~~~Z}~, 3, and RudCO)10- ~3-~2:g2:~2-CsH5-(~z-CCH3CH~}), 4, have been prepared and characterized both spectro scopically and by means of single-crystal X-ray diffraction. The presence of the propenyl substituent(s) on the aromatic ligands results in the observed preference of the rings toward a facial coordination mode, formally donating all their n-electrons to the metal cluster unit.

Braga D., Byrne J.J., Grepioni F., Parisini E., Dyson P.J., Gaede P.E., et al. (1995). Synthesis and Characterization of RU3 and RU4 Clusters with Isopropenylbenzene and Diisopropenylbenzene Ligands. ORGANOMETALLICS, 14(10), 4892-4898 [10.1021/om00010a060].

Synthesis and Characterization of RU3 and RU4 Clusters with Isopropenylbenzene and Diisopropenylbenzene Ligands

Braga D.;Grepioni F.;Parisini E.;
1995

Abstract

The four clusters Ru~(C~)~~~-~~:~~:~~-C~H~-{~~-CCH~CH~)Z-~,~~, 1, RU~(CO)~~~-~~:~~:~~- CsH4-{7;12-CCH3CHz}~-1,3), 2, Ru~(CO)~~~-~~:~~:~~-~~H~-{~~-~~H~~~Z}~, 3, and RudCO)10- ~3-~2:g2:~2-CsH5-(~z-CCH3CH~}), 4, have been prepared and characterized both spectro scopically and by means of single-crystal X-ray diffraction. The presence of the propenyl substituent(s) on the aromatic ligands results in the observed preference of the rings toward a facial coordination mode, formally donating all their n-electrons to the metal cluster unit.
1995
Braga D., Byrne J.J., Grepioni F., Parisini E., Dyson P.J., Gaede P.E., et al. (1995). Synthesis and Characterization of RU3 and RU4 Clusters with Isopropenylbenzene and Diisopropenylbenzene Ligands. ORGANOMETALLICS, 14(10), 4892-4898 [10.1021/om00010a060].
Braga D.; Byrne J.J.; Grepioni F.; Parisini E.; Dyson P.J.; Gaede P.E.; Johnson B.F.G.; Reed D.
File in questo prodotto:
Eventuali allegati, non sono esposti

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/916056
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 13
  • ???jsp.display-item.citation.isi??? ND
social impact