The heptanuclear clusters [Ru7C(CO)(16)(C9H8)] and [Ru7C(CO)(16)(C12H12)] have been isolated from the reaction between [Ru-3(CO)(12)] and isopropenyl- or 1,3-diisopropenyl-benzene and their crystal structures determined: the Ru-7 cores represent rare examples of spiked octahedra; the organo-ligands are bound through all four pi bonds to a metal face and through two sigma bonds to the ruthenium spike, donating a total of ten electrons.

BLAKE, A.J., DYSON, P.J., GAEDE, P.E., JOHNSON, B., BRAGA, D., PARISINI, E. (1995). SYNTHESIS AND CRYSTALLOGRAPHIC CHARACTERIZATION OF [RU7C(CO)(16)(C9H8)] AND [RU7C(CO)(16)(C12H12)] - FACIAL PI-BONDING AND SIGMA BONDING FROM THE SAME RING-SYSTEM. JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS, 20, 3431-3432 [10.1039/dt9950003431].

SYNTHESIS AND CRYSTALLOGRAPHIC CHARACTERIZATION OF [RU7C(CO)(16)(C9H8)] AND [RU7C(CO)(16)(C12H12)] - FACIAL PI-BONDING AND SIGMA BONDING FROM THE SAME RING-SYSTEM

BRAGA, D;PARISINI, E
1995

Abstract

The heptanuclear clusters [Ru7C(CO)(16)(C9H8)] and [Ru7C(CO)(16)(C12H12)] have been isolated from the reaction between [Ru-3(CO)(12)] and isopropenyl- or 1,3-diisopropenyl-benzene and their crystal structures determined: the Ru-7 cores represent rare examples of spiked octahedra; the organo-ligands are bound through all four pi bonds to a metal face and through two sigma bonds to the ruthenium spike, donating a total of ten electrons.
1995
BLAKE, A.J., DYSON, P.J., GAEDE, P.E., JOHNSON, B., BRAGA, D., PARISINI, E. (1995). SYNTHESIS AND CRYSTALLOGRAPHIC CHARACTERIZATION OF [RU7C(CO)(16)(C9H8)] AND [RU7C(CO)(16)(C12H12)] - FACIAL PI-BONDING AND SIGMA BONDING FROM THE SAME RING-SYSTEM. JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS, 20, 3431-3432 [10.1039/dt9950003431].
BLAKE, AJ; DYSON, PJ; GAEDE, PE; JOHNSON, BFG; BRAGA, D; PARISINI, E
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/915956
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