Application of the ligand polyhedral model (LPM) to dicobalt octacarbonyl, [Co2(CO)8], leads to an explanation of the mu-2-bridged structure that the molecule adopts in the solid state and also of the isomeric forms which coexist in equilibrium in solution. It further provides a convenient explanation of both the observed low energy interconversion of these isomers and the fluxional behaviour they exhibit.
JOHNSON, B., PARISINI, E. (1992). APPLICATION OF THE LIGAND POLYHEDRAL MODEL TO DICOBALT OCTACARBONYL. INORGANICA CHIMICA ACTA, 198, 345-349 [10.1016/S0020-1693(00)92376-4].
APPLICATION OF THE LIGAND POLYHEDRAL MODEL TO DICOBALT OCTACARBONYL
PARISINI, E
1992
Abstract
Application of the ligand polyhedral model (LPM) to dicobalt octacarbonyl, [Co2(CO)8], leads to an explanation of the mu-2-bridged structure that the molecule adopts in the solid state and also of the isomeric forms which coexist in equilibrium in solution. It further provides a convenient explanation of both the observed low energy interconversion of these isomers and the fluxional behaviour they exhibit.File in questo prodotto:
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