Application of the ligand polyhedral model (LPM) to dicobalt octacarbonyl, [Co2(CO)8], leads to an explanation of the mu-2-bridged structure that the molecule adopts in the solid state and also of the isomeric forms which coexist in equilibrium in solution. It further provides a convenient explanation of both the observed low energy interconversion of these isomers and the fluxional behaviour they exhibit.
APPLICATION OF THE LIGAND POLYHEDRAL MODEL TO DICOBALT OCTACARBONYL / JOHNSON, BFG; PARISINI, E. - In: INORGANICA CHIMICA ACTA. - ISSN 0020-1693. - ELETTRONICO. - 198:(1992), pp. 345-349. [10.1016/S0020-1693(00)92376-4]
APPLICATION OF THE LIGAND POLYHEDRAL MODEL TO DICOBALT OCTACARBONYL
PARISINI, E
1992
Abstract
Application of the ligand polyhedral model (LPM) to dicobalt octacarbonyl, [Co2(CO)8], leads to an explanation of the mu-2-bridged structure that the molecule adopts in the solid state and also of the isomeric forms which coexist in equilibrium in solution. It further provides a convenient explanation of both the observed low energy interconversion of these isomers and the fluxional behaviour they exhibit.File in questo prodotto:
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