The crystal structures of some high nuclearity carbonyl cluster anions of rhodium and cobalt have been investigated by means of empirical packing potential energy calculations, van der Waals volume analysis and computer graphics. Data was retrieved from the Cambridge structural Database. The relationship between shape, size and charge of the component ions and the formation of preferential aggregates in the crystalline solid has been analyzed.
BRAGA, D., GREPIONI, F., MARSHALL, P., PARISINI, E. (1993). MOLECULAR SALTS OF HIGH-NUCLEARITY CLUSTER ANIONS - CATION CONTROL ON THE CRYSTAL-STRUCTURE. INORGANICA CHIMICA ACTA, 213(1-2), 121-127 [10.1016/S0020-1693(00)83822-0].
MOLECULAR SALTS OF HIGH-NUCLEARITY CLUSTER ANIONS - CATION CONTROL ON THE CRYSTAL-STRUCTURE
BRAGA, D;GREPIONI, F;PARISINI, E
1993
Abstract
The crystal structures of some high nuclearity carbonyl cluster anions of rhodium and cobalt have been investigated by means of empirical packing potential energy calculations, van der Waals volume analysis and computer graphics. Data was retrieved from the Cambridge structural Database. The relationship between shape, size and charge of the component ions and the formation of preferential aggregates in the crystalline solid has been analyzed.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
