The dynamic behaviour shown by transition metal arene-clusters in the solid state has been investigated by means of potential energy barrier calculations showing that the ease of reorientation of the arene ligands depends primarily on the shape of the fragment and not on crystalline properties. Thermal motion analysis has been used to study atomic motion about the equilibrium position.
DYNAMIC PROCESSES IN CRYSTALS OF TRANSITION-METAL CLUSTERS / BRAGA, D; GREPIONI, F; PARISINI, E; RIGHI, S. - In: MATERIALS CHEMISTRY AND PHYSICS. - ISSN 0254-0584. - ELETTRONICO. - 29:1-4(1991), pp. 165-173. [10.1016/0254-0584(91)90013-K]
DYNAMIC PROCESSES IN CRYSTALS OF TRANSITION-METAL CLUSTERS
BRAGA, D;GREPIONI, F;PARISINI, E;
1991
Abstract
The dynamic behaviour shown by transition metal arene-clusters in the solid state has been investigated by means of potential energy barrier calculations showing that the ease of reorientation of the arene ligands depends primarily on the shape of the fragment and not on crystalline properties. Thermal motion analysis has been used to study atomic motion about the equilibrium position.File in questo prodotto:
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