A novel rearrangement of cycloketoxime esters to cyano-containing benzoates beyond the traditional Beckmann and Neber rearrangement process has been established in the presence of photocatalysis catalysis. This SET-induced structural reorganization of cycloketoxime esters is perfectly an atom economic process and distinguished by mild and safe reaction conditions that avoid acid, base and toxic cyanide salts.
Zhao B., Chen C., Lv J., Li Z., Yuan Y., Shi Z. (2018). Photoinduced fragmentation-rearrangement sequence of cycloketoxime esters. ORGANIC CHEMISTRY FRONTIERS, 5(18), 2719-2722 [10.1039/c8qo00747k].
Photoinduced fragmentation-rearrangement sequence of cycloketoxime esters
Zhao B.;Shi Z.
2018
Abstract
A novel rearrangement of cycloketoxime esters to cyano-containing benzoates beyond the traditional Beckmann and Neber rearrangement process has been established in the presence of photocatalysis catalysis. This SET-induced structural reorganization of cycloketoxime esters is perfectly an atom economic process and distinguished by mild and safe reaction conditions that avoid acid, base and toxic cyanide salts.File in questo prodotto:
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