We have synthesized thienylene- and phenylene-based oligomers displaying solid-state photoluminescence efficiencies up to 70% and photoluminescence frequencies which cover the entire visible range All compounds contain one central nonaromatic thienyl-1,1-dioxide moiety in the main chain. The tuning of the light-emission frequency was achieved by progressively varying the degree of π-π electron delocalization between the nonaromatic moiety and the α-linked aromatic rings. All compounds displayed greater electron affinities than thienylene or phenylene oligomers of comparable lengths, as deduced from the reduction potentials measured by cyclic voltammetry.
Barbarella G., Favaretto L., Sotgiu G., Zambianchi M., Bongini A., Arbizzani C., et al. (2000). Tuning solid-state photoluminescence frequencies and efficiencies of oligomers containing one central thiophene-S,S-dioxide unit. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 122(48), 11971-11978 [10.1021/ja002037p].
Tuning solid-state photoluminescence frequencies and efficiencies of oligomers containing one central thiophene-S,S-dioxide unit
Favaretto L.;Sotgiu G.;Zambianchi M.;Bongini A.;Arbizzani C.Investigation
;Mastragostino M.;Gigli G.;
2000
Abstract
We have synthesized thienylene- and phenylene-based oligomers displaying solid-state photoluminescence efficiencies up to 70% and photoluminescence frequencies which cover the entire visible range All compounds contain one central nonaromatic thienyl-1,1-dioxide moiety in the main chain. The tuning of the light-emission frequency was achieved by progressively varying the degree of π-π electron delocalization between the nonaromatic moiety and the α-linked aromatic rings. All compounds displayed greater electron affinities than thienylene or phenylene oligomers of comparable lengths, as deduced from the reduction potentials measured by cyclic voltammetry.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
