Ab initio calculations and experimental oxidation and reduction potentials show that the functionalization of thiophene to the corresponding S-oxide leads to only a minor change in ionization potential but to a dramatic increase in the electron affinity.
Bongini A., Barbarella G., Zambianchi M., Arbizzani C., Mastragostino M. (2000). Thiophene S-oxides: Orbital energies and electrochemical properties. CHEMICAL COMMUNICATIONS, -(6), 439-440 [10.1039/a909390g].
Thiophene S-oxides: Orbital energies and electrochemical properties
Bongini A.;Zambianchi M.;Arbizzani C.Investigation
;Mastragostino M.
2000
Abstract
Ab initio calculations and experimental oxidation and reduction potentials show that the functionalization of thiophene to the corresponding S-oxide leads to only a minor change in ionization potential but to a dramatic increase in the electron affinity.File in questo prodotto:
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