The 3,3′-, 3,4′- and 4,4′-dimethyl-2,2′-bithiophenes, prepared in very pure form and characterized by 13C NMR, were used as starting molecules for electrochemical polymerization of poly(3-methylthiophenes). The optical properties of the resulting polymers were interpreted on the basis of the conformation of the starting dimers determined by force field MMP2 calculations. © 1992.
Arbizzani C., Barbarella G., Bongini A., Mastragostino M., Zambianchi M. (1992). Electrochemical and optical properties of poly(3-methylthiophenes) electrosynthesized by 3,3′-, 3,4′- and 4,4′-dimethyl-2,2′-bithiophenes. SYNTHETIC METALS, 52(3), 329-339 [10.1016/0379-6779(92)90032-E].
Electrochemical and optical properties of poly(3-methylthiophenes) electrosynthesized by 3,3′-, 3,4′- and 4,4′-dimethyl-2,2′-bithiophenes
Arbizzani C.Primo
Investigation
;Bongini A.Methodology
;Mastragostino M.Conceptualization
;Zambianchi M.Membro del Collaboration Group
1992
Abstract
The 3,3′-, 3,4′- and 4,4′-dimethyl-2,2′-bithiophenes, prepared in very pure form and characterized by 13C NMR, were used as starting molecules for electrochemical polymerization of poly(3-methylthiophenes). The optical properties of the resulting polymers were interpreted on the basis of the conformation of the starting dimers determined by force field MMP2 calculations. © 1992.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
