The diversity of processes that contribute to an x‐ray fluorescence spectrum make it difficult to obtain an accurate estimate of the line intensities needed to determine the sample composition in XRF analysis. The radiative contributions forming the spectrum are produced by the interactions that x‐ray photons undergo with the atoms of the sample. Many multiple scattering terms contribute to the continuous portions of spectrum that overlap the lines of interest. The lines themselves are formed by the overlap of many narrow (discrete) contributions and some continuous ones: one ‘primary intensity’ plus several enhancement terms. The lines can also interfere with other neighbouring lines produced in the sample. The resulting spectrum, sufficiently complicated at this stage, is still modified in a complex way by the influence of the detector response and successive digitalization by the multi‐channel analyser. The difficulties that such spectral complexity introduces in the process of extracting the ‘primary fluorescence intensity’ from the experimental spectrum can be overcome by using a theoretical spectrum of reference that, in this paper, was calculated using the code SHAPE. Such a theoretical spectrum has the property that all the single contributions are well known, and therefore can be used to estimate correctly the fraction of ‘primary fluorescence intensity’ under any experimental line of interest in the real spectrum enclosed between two given energy channels. Since the theoretical spectrum can be computed only for a known composition, the calculated fraction can be initially obtained by feeding SHAPE with an arbitrary composition. The fraction estimated with the theoretical spectrum is used to correct the corresponding peak area in the experimental measured spectrum, which in turn is used to obtain a new calculated composition. This result is used to feed a new spectrum computation, defining an iterative method that converges to the unknown composition. The theoretical details of this iterative method are described and some experimental examples of EDXRF analysis using this technique are given. The advantages of the method for treating some paradigmatic cases of analysis are also illustrated. Copyright © 1995 John Wiley & Sons, Ltd.
EDXRF procedure for quantitative analysis matching theoretically generated reference spectra to measured spectra / Fernandez J.E.; Tartari A.. - In: X-RAY SPECTROMETRY. - ISSN 0049-8246. - STAMPA. - 24:6(1995), pp. 277-282. [10.1002/xrs.1300240602]
EDXRF procedure for quantitative analysis matching theoretically generated reference spectra to measured spectra
Fernandez J. E.
Primo
Writing – Original Draft Preparation
;
1995
Abstract
The diversity of processes that contribute to an x‐ray fluorescence spectrum make it difficult to obtain an accurate estimate of the line intensities needed to determine the sample composition in XRF analysis. The radiative contributions forming the spectrum are produced by the interactions that x‐ray photons undergo with the atoms of the sample. Many multiple scattering terms contribute to the continuous portions of spectrum that overlap the lines of interest. The lines themselves are formed by the overlap of many narrow (discrete) contributions and some continuous ones: one ‘primary intensity’ plus several enhancement terms. The lines can also interfere with other neighbouring lines produced in the sample. The resulting spectrum, sufficiently complicated at this stage, is still modified in a complex way by the influence of the detector response and successive digitalization by the multi‐channel analyser. The difficulties that such spectral complexity introduces in the process of extracting the ‘primary fluorescence intensity’ from the experimental spectrum can be overcome by using a theoretical spectrum of reference that, in this paper, was calculated using the code SHAPE. Such a theoretical spectrum has the property that all the single contributions are well known, and therefore can be used to estimate correctly the fraction of ‘primary fluorescence intensity’ under any experimental line of interest in the real spectrum enclosed between two given energy channels. Since the theoretical spectrum can be computed only for a known composition, the calculated fraction can be initially obtained by feeding SHAPE with an arbitrary composition. The fraction estimated with the theoretical spectrum is used to correct the corresponding peak area in the experimental measured spectrum, which in turn is used to obtain a new calculated composition. This result is used to feed a new spectrum computation, defining an iterative method that converges to the unknown composition. The theoretical details of this iterative method are described and some experimental examples of EDXRF analysis using this technique are given. The advantages of the method for treating some paradigmatic cases of analysis are also illustrated. Copyright © 1995 John Wiley & Sons, Ltd.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
