The new allylaminosilanes 2a-c, derived from chiral amines, react with benzaldehyde and pivalaldehyde in the presence of SnCl4 to give homoallylic alcohols 4a-b with enantiomeric excesses of up to 30%.
Bonini B.F., Comes-Franchini M., Fochi M., Mazzanti G., Ricci A., Varchi G. (1998). New chiral allylaminosilanes and their use in asymmetric Sakurai reactions. TETRAHEDRON-ASYMMETRY, 9(17), 2979-2981 [10.1016/S0957-4166(98)00327-9].
New chiral allylaminosilanes and their use in asymmetric Sakurai reactions
Bonini B. F.;Comes-Franchini M.;Fochi M.;Mazzanti G.;Ricci A.;Varchi G.
1998
Abstract
The new allylaminosilanes 2a-c, derived from chiral amines, react with benzaldehyde and pivalaldehyde in the presence of SnCl4 to give homoallylic alcohols 4a-b with enantiomeric excesses of up to 30%.File in questo prodotto:
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