The new allylaminosilanes 2a-c, derived from chiral amines, react with benzaldehyde and pivalaldehyde in the presence of SnCl4 to give homoallylic alcohols 4a-b with enantiomeric excesses of up to 30%.
New chiral allylaminosilanes and their use in asymmetric Sakurai reactions / Bonini B.F.; Comes-Franchini M.; Fochi M.; Mazzanti G.; Ricci A.; Varchi G.. - In: TETRAHEDRON-ASYMMETRY. - ISSN 0957-4166. - STAMPA. - 9:17(1998), pp. 2979-2981. [10.1016/S0957-4166(98)00327-9]
New chiral allylaminosilanes and their use in asymmetric Sakurai reactions
Bonini B. F.;Comes-Franchini M.;Fochi M.;Mazzanti G.;Ricci A.;Varchi G.
1998
Abstract
The new allylaminosilanes 2a-c, derived from chiral amines, react with benzaldehyde and pivalaldehyde in the presence of SnCl4 to give homoallylic alcohols 4a-b with enantiomeric excesses of up to 30%.File in questo prodotto:
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