A detailed investigation of the desilylation of (Z)-α-dimethylphenylsilyl vinyl sulfides with fluoride ion has shown that in substrates containing an electron-withdrawing group β to the sulfur, phenyl group migration occurs as a result of a fluoride ion catalyzed retro-Michael reaction.

Bonini B.F., Franchini M.C., Fochi M., Mazzanti G., Ricci A. (1997). Desilylation of (Z)-α-dimethylphenylsilyl vinyl sulfides with fluoride ion: Revised mechanism for phenyl group migration in substrates containing an electron-withdrawing group β to the sulfur. JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I, 1997(21), 3211-3217.

Desilylation of (Z)-α-dimethylphenylsilyl vinyl sulfides with fluoride ion: Revised mechanism for phenyl group migration in substrates containing an electron-withdrawing group β to the sulfur

Bonini B. F.;Franchini M. C.;Fochi M.;Mazzanti G.;Ricci A.
1997

Abstract

A detailed investigation of the desilylation of (Z)-α-dimethylphenylsilyl vinyl sulfides with fluoride ion has shown that in substrates containing an electron-withdrawing group β to the sulfur, phenyl group migration occurs as a result of a fluoride ion catalyzed retro-Michael reaction.
1997
Bonini B.F., Franchini M.C., Fochi M., Mazzanti G., Ricci A. (1997). Desilylation of (Z)-α-dimethylphenylsilyl vinyl sulfides with fluoride ion: Revised mechanism for phenyl group migration in substrates containing an electron-withdrawing group β to the sulfur. JOURNAL OF THE CHEMICAL SOCIETY. PERKIN TRANSACTIONS. I, 1997(21), 3211-3217.
Bonini B.F.; Franchini M.C.; Fochi M.; Mazzanti G.; Ricci A.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/899351
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