ω-Haloacylsilanes 1 were selectively transformed via thioacylsilanes into Z-silyl-enethiols 4 with solid sodium hydrogen carbonate or into 2-silylthiacycloalk-2-enes5 of common to large ring size with solid sodium hydroxide. Compounds 5 underwent protiodesilylation.
Bonini B.F., Comes-Franchini M., Fochi M., Mazzanti G., Ricci A. (1996). Chemistry of silyl thioketones part 9. 1 A new selective synthesis of 1-silyl-1-enethiols and of 2-silyl-thiacycloalk-2-enes of common to large ring size. TETRAHEDRON, 52(13), 4803-4816 [10.1016/0040-4020(96)00148-2].
Chemistry of silyl thioketones part 9. 1 A new selective synthesis of 1-silyl-1-enethiols and of 2-silyl-thiacycloalk-2-enes of common to large ring size
Bonini B. F.;Comes-Franchini M.;Fochi M.;Mazzanti G.;Ricci A.
1996
Abstract
ω-Haloacylsilanes 1 were selectively transformed via thioacylsilanes into Z-silyl-enethiols 4 with solid sodium hydrogen carbonate or into 2-silylthiacycloalk-2-enes5 of common to large ring size with solid sodium hydroxide. Compounds 5 underwent protiodesilylation.File in questo prodotto:
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