ω-Haloacylsilanes 1 were selectively transformed via thioacylsilanes into Z-silyl-enethiols 4 with solid sodium hydrogen carbonate or into 2-silylthiacycloalk-2-enes5 of common to large ring size with solid sodium hydroxide. Compounds 5 underwent protiodesilylation.

Chemistry of silyl thioketones part 9. 1 A new selective synthesis of 1-silyl-1-enethiols and of 2-silyl-thiacycloalk-2-enes of common to large ring size / Bonini B.F.; Comes-Franchini M.; Fochi M.; Mazzanti G.; Ricci A.. - In: TETRAHEDRON. - ISSN 0040-4020. - STAMPA. - 52:13(1996), pp. 4803-4816. [10.1016/0040-4020(96)00148-2]

Chemistry of silyl thioketones part 9. 1 A new selective synthesis of 1-silyl-1-enethiols and of 2-silyl-thiacycloalk-2-enes of common to large ring size

Bonini B. F.;Comes-Franchini M.;Fochi M.;Mazzanti G.;Ricci A.
1996

Abstract

ω-Haloacylsilanes 1 were selectively transformed via thioacylsilanes into Z-silyl-enethiols 4 with solid sodium hydrogen carbonate or into 2-silylthiacycloalk-2-enes5 of common to large ring size with solid sodium hydroxide. Compounds 5 underwent protiodesilylation.
1996
Chemistry of silyl thioketones part 9. 1 A new selective synthesis of 1-silyl-1-enethiols and of 2-silyl-thiacycloalk-2-enes of common to large ring size / Bonini B.F.; Comes-Franchini M.; Fochi M.; Mazzanti G.; Ricci A.. - In: TETRAHEDRON. - ISSN 0040-4020. - STAMPA. - 52:13(1996), pp. 4803-4816. [10.1016/0040-4020(96)00148-2]
Bonini B.F.; Comes-Franchini M.; Fochi M.; Mazzanti G.; Ricci A.
File in questo prodotto:
Eventuali allegati, non sono esposti

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/899343
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 20
  • ???jsp.display-item.citation.isi??? ND
social impact