Thietanols, thiolanols and thianols can be obtained by a fluoride-mediated cyclization of Z-α-silyl vinyl sulphides containing a -carbonylic function in the chain bonded to the sulfur. The condensative cyclization of -carboxy-Z-α-silyl enethiols leads to unsaturated silylated thiolactones.
Bonini B.F., Franchini M.C., Fochi M., Mangini S., Mazzanti G., Ricci A. (1999). Enethiolizable thioacylsilanes as intermediates for the synthesis of thietanols, thiolanols, thianols and thiolactones. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 153-154(1), 315-316 [10.1080/10426509908546448].
Enethiolizable thioacylsilanes as intermediates for the synthesis of thietanols, thiolanols, thianols and thiolactones
Bonini B. F.;Franchini M. C.;Fochi M.;Mazzanti G.;Ricci A.
1999
Abstract
Thietanols, thiolanols and thianols can be obtained by a fluoride-mediated cyclization of Z-α-silyl vinyl sulphides containing a -carbonylic function in the chain bonded to the sulfur. The condensative cyclization of -carboxy-Z-α-silyl enethiols leads to unsaturated silylated thiolactones.File in questo prodotto:
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