Thietanols, thiolanols and thianols can be obtained by a fluoride-mediated cyclization of Z-α-silyl vinyl sulphides containing a -carbonylic function in the chain bonded to the sulfur. The condensative cyclization of -carboxy-Z-α-silyl enethiols leads to unsaturated silylated thiolactones.
Enethiolizable thioacylsilanes as intermediates for the synthesis of thietanols, thiolanols, thianols and thiolactones / Bonini B.F.; Franchini M.C.; Fochi M.; Mangini S.; Mazzanti G.; Ricci A.. - In: PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. - ISSN 1042-6507. - STAMPA. - 153-154:1(1999), pp. 315-316. [10.1080/10426509908546448]
Enethiolizable thioacylsilanes as intermediates for the synthesis of thietanols, thiolanols, thianols and thiolactones
Bonini B. F.;Franchini M. C.;Fochi M.;Mazzanti G.;Ricci A.
1999
Abstract
Thietanols, thiolanols and thianols can be obtained by a fluoride-mediated cyclization of Z-α-silyl vinyl sulphides containing a -carbonylic function in the chain bonded to the sulfur. The condensative cyclization of -carboxy-Z-α-silyl enethiols leads to unsaturated silylated thiolactones.File in questo prodotto:
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