Grignard reagents display useful diversity in their reactions with nitroarenes. Depending on the organomagnesium species used, these reactions, the results of which can be predicted from mechanistic studies, may lead to significantly diverse products (see scheme), and can be tailored towards the synthesis of substituted nitroarenes, indoles, and diarylamines. FG = functional group.
Reactions between organomagnesium reagents and nitroarenes: Past, present, and future / Ricci A.; Fochi M.. - In: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION. - ISSN 1433-7851. - STAMPA. - 42:13(2003), pp. 1444-1446. [10.1002/anie.200201618]
Reactions between organomagnesium reagents and nitroarenes: Past, present, and future
Ricci A.;Fochi M.
2003
Abstract
Grignard reagents display useful diversity in their reactions with nitroarenes. Depending on the organomagnesium species used, these reactions, the results of which can be predicted from mechanistic studies, may lead to significantly diverse products (see scheme), and can be tailored towards the synthesis of substituted nitroarenes, indoles, and diarylamines. FG = functional group.File in questo prodotto:
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