The reaction of alkyl, cycloalkyl, aromatic, heteroaromatic and α,β-unsaturated acylsilanes 1-7 and of homochiral acylsilanes 15 and 16 with the complex vinylmagnesium bromide/CeCl3 affords the silylated allylic alcohols in satisfactory to excellent yields.
Bonini B.F., Comes-Franchini M., Fochi M., Mazzanti G., Ricci A., Varchi G. (2000). Cerium(III) chloride-mediated vinylation of acylsilanes: A convenient new entry to silylated allylic alcohols. SYNLETT, 2000(11), 1688-1690.
Cerium(III) chloride-mediated vinylation of acylsilanes: A convenient new entry to silylated allylic alcohols
Bonini B. F.;Comes-Franchini M.;Fochi M.;Mazzanti G.;Ricci A.;Varchi G.
2000
Abstract
The reaction of alkyl, cycloalkyl, aromatic, heteroaromatic and α,β-unsaturated acylsilanes 1-7 and of homochiral acylsilanes 15 and 16 with the complex vinylmagnesium bromide/CeCl3 affords the silylated allylic alcohols in satisfactory to excellent yields.File in questo prodotto:
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