In situ monitoring of mechanochemical reactions between dicyandiamide (DCD) and CuX2 salts (X = Cl-, NO3-), for the preparation of compounds of agrochemical interest, showed the appearance of a number of phases. It is demonstrated that milling conditions, such as the amount of water added in wet grinding and/or the milling frequency, may affect the course of the mechanochemical reactions, and drive the reaction towards the formation of different products. It has been possible to discover by in situ monitored experiments two novel crystalline forms, namely the neutral complexes [Cu(DCD)(2)(OH2)(2)(NO3)(2)] (2) and [Cu(DCD)(2)(OH2)Cl-2]center dot H2O (4), in addition to the previously known molecular salt [Cu(DCD)(2)(OH2)(2)] [NO3](2)center dot 2H(2)O (1, DIVWAG) and neutral complex [Cu(DCD)(2)(OH2)Cl-2] (3, AQCYCU), for which no synthesis conditions were available. Compounds 2 and 4 were fully characterized via a combination of solid-state techniques, including X-ray diffraction, Raman spectroscopy and TGA.

Too much water? Not enough? In situ monitoring of the mechanochemical reaction of copper salts with dicyandiamide / Lucia Casali; Torvid Feiler; Maria Heilmann; Dario Braga; Franziska Emmerling; Fabrizia Grepioni. - In: CRYSTENGCOMM. - ISSN 1466-8033. - ELETTRONICO. - 24:6(2022), pp. 1292-1298. [10.1039/d1ce01670a]

Too much water? Not enough? In situ monitoring of the mechanochemical reaction of copper salts with dicyandiamide

Lucia Casali;Dario Braga;Fabrizia Grepioni
2022

Abstract

In situ monitoring of mechanochemical reactions between dicyandiamide (DCD) and CuX2 salts (X = Cl-, NO3-), for the preparation of compounds of agrochemical interest, showed the appearance of a number of phases. It is demonstrated that milling conditions, such as the amount of water added in wet grinding and/or the milling frequency, may affect the course of the mechanochemical reactions, and drive the reaction towards the formation of different products. It has been possible to discover by in situ monitored experiments two novel crystalline forms, namely the neutral complexes [Cu(DCD)(2)(OH2)(2)(NO3)(2)] (2) and [Cu(DCD)(2)(OH2)Cl-2]center dot H2O (4), in addition to the previously known molecular salt [Cu(DCD)(2)(OH2)(2)] [NO3](2)center dot 2H(2)O (1, DIVWAG) and neutral complex [Cu(DCD)(2)(OH2)Cl-2] (3, AQCYCU), for which no synthesis conditions were available. Compounds 2 and 4 were fully characterized via a combination of solid-state techniques, including X-ray diffraction, Raman spectroscopy and TGA.
2022
Too much water? Not enough? In situ monitoring of the mechanochemical reaction of copper salts with dicyandiamide / Lucia Casali; Torvid Feiler; Maria Heilmann; Dario Braga; Franziska Emmerling; Fabrizia Grepioni. - In: CRYSTENGCOMM. - ISSN 1466-8033. - ELETTRONICO. - 24:6(2022), pp. 1292-1298. [10.1039/d1ce01670a]
Lucia Casali; Torvid Feiler; Maria Heilmann; Dario Braga; Franziska Emmerling; Fabrizia Grepioni
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11585/897557
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