A copper-containing metal organic framework was prepared using the new organic linker 5-(2-{[(prop-2-yn-1-yloxy)carbonyl]-amino} ethoxy)isophthalic acid [1,3-H2YBDC (where Y = alkYne and BDC = Benzene DiCarboxylate)] and functionalized with gold particles by reaction with HAuCl4 under thermal treatment in methanol. The resulting system was investigated by complementary techniques to obtain information on its structure and morphology. In the present work, x-ray photoelectron spectroscopy (XPS) was employed to analyze the chemical composition of a representative specimen. Besides wide scan spectra, data obtained by the analysis of the C 1s, O 1s, N 1s, Cu 2p, and Au 4f signals are presented and critically discussed. The results highlight the reduction of Au(III) to mostly Au(I) species. Overall, the data presented herein may act as useful guidelines for the eventual tailoring of material properties and their possible implementation toward functional applications in heterogeneous catalysis.
Propargyl carbamate-functionalized Cu(II)-metal organic framework after reaction with chloroauric acid: An x-ray photoelectron spectroscopy data record
Cassani, MC
Conceptualization
;Gambassi, F;Ballarin, B;Nanni, D;Boanini, E;
2022
Abstract
A copper-containing metal organic framework was prepared using the new organic linker 5-(2-{[(prop-2-yn-1-yloxy)carbonyl]-amino} ethoxy)isophthalic acid [1,3-H2YBDC (where Y = alkYne and BDC = Benzene DiCarboxylate)] and functionalized with gold particles by reaction with HAuCl4 under thermal treatment in methanol. The resulting system was investigated by complementary techniques to obtain information on its structure and morphology. In the present work, x-ray photoelectron spectroscopy (XPS) was employed to analyze the chemical composition of a representative specimen. Besides wide scan spectra, data obtained by the analysis of the C 1s, O 1s, N 1s, Cu 2p, and Au 4f signals are presented and critically discussed. The results highlight the reduction of Au(III) to mostly Au(I) species. Overall, the data presented herein may act as useful guidelines for the eventual tailoring of material properties and their possible implementation toward functional applications in heterogeneous catalysis.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
