The weak 2v3 overtone band of the three isotopomers of cyanogen iodide, I12C14N, I13C14N, and I12C15N, has been recorded in the range from 4200 to 4400 cm-1 with a resolution of 0.02 cm-1 using a Fourier transform infrared spectrometer. The following band origins have been determined from the analysis of the spectra: v0(I12C14N)=4332.8368 cm-1, v0 (I13C14N)=4235.7355 cm-1, and v0 (I12C15N)=4274.2851 cm-1. This allowed us to achieve complete knowledge of the energies for all levels of ICN corresponding to double vibrational excitation. An improved evaluation of the quartic force field of cyanogen iodide has been performed using the new data obtained together with those already known from previous works.
Bizzocchi, L., Esposti, C.D., Mazzavillani, A., Tamassia, F. (2003). Fourier transform infrared spectroscopy of the 2v3 overtone band of different ICN isotopomers: An improved evaluation of the anharmonic force field of cyanogen iodide. JOURNAL OF MOLECULAR SPECTROSCOPY, 221(2), 213-220 [10.1016/S0022-2852(03)00208-X].
Fourier transform infrared spectroscopy of the 2v3 overtone band of different ICN isotopomers: An improved evaluation of the anharmonic force field of cyanogen iodide
Bizzocchi L.;Mazzavillani A.;Tamassia F.
2003
Abstract
The weak 2v3 overtone band of the three isotopomers of cyanogen iodide, I12C14N, I13C14N, and I12C15N, has been recorded in the range from 4200 to 4400 cm-1 with a resolution of 0.02 cm-1 using a Fourier transform infrared spectrometer. The following band origins have been determined from the analysis of the spectra: v0(I12C14N)=4332.8368 cm-1, v0 (I13C14N)=4235.7355 cm-1, and v0 (I12C15N)=4274.2851 cm-1. This allowed us to achieve complete knowledge of the energies for all levels of ICN corresponding to double vibrational excitation. An improved evaluation of the quartic force field of cyanogen iodide has been performed using the new data obtained together with those already known from previous works.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
